Fireworks
use black powder, also known as gunpowder. They are classed as low explosives
in contrast to the infinitely more powerful high explosives such as TNT
and dynamite.
In
pyrotechnics an oxidizer and a fuel react together to produce light.
Bombs
and mortars
The central tool in fireworks is the shell or "bomb". A bomb
is usually round or cylindrical in shape and is covered with a casing
of cardboard and/or plastic and twine - with a lift-charge beneath it
made from black powder.
The
bomb is inserted into a mortar (a gun-like cylinder with a bottom plug)
made of cardboard, plastic or steel for the larger bombs. The mortar serves
as the bomb's launching pad. The mortars and bombs are wired to a central
firing booth, from which the bombs' lift-charges are ignited electrically
throughout the show.
When
the lift-charge explodes, the bomb shoots out of the mortar up into the
air. In the core of the shell is another exploding charge with a delay
fuse. When the shell is fired from the mortar, it in turn ignites the
delay fuse, which is cut to a length that will set off the explosive charge
inside the shell at the right height and the right time.
The
explosive charge at the centre of the bomb is made of black powder or
flash powder (composed of potassium perchlorate, aluminum powder, and/or
magnesium which, upon ignition, creates a violent explosion combined with
a flash). The explosion sends the burning stars out in a particular pattern
determined by the way the shell was packed by the bomb maker - creating
the colourful effect the crowd sees.
Stars
Each bomb is very carefully constructed in a fireworks' factory. A chemist
produces the powders and presses or rolls them into pellets called stars
which are spherical, cylindrical or cube-shaped.
When
lit, the stars produce a brilliant ball of fire. They are made with oxygen-rich
components such as strontium nitrate, potassium perchlorate, potassium
nitrate and potassium chlorate. The star contains both oxidizer and fuel.
When the oxidizer burns with the fuel made of charcoal, titanium powder
and aluminum powder or other metal or carbon-based mixtures, the reaction
to the burning of both oxidizer and fuel creates the effect of colour.
The
shell maker assembles the stars within the shell casing, in a careful
configuration that determines the height at which the star will be expelled
and so as to produce any desired effects (such as the star being expelled
in a particular shape such as a heart or circle).
The
formulas
There are only about 100 top fireworks manufacturers in the world. Each
company's formulas are closely-guarded secrets. The chemical and powder
recipes are often handed down through generations of families. The colour,
animation, sound and flight pattern of each shell depends on its design
and on the blend of its chemical ingredients.
The
colors
In fireworks there are six common colors, made by adding a specific chemical
compound.
- White
is produced by magnesium or aluminum or titanium
- Yellow
by sodium salts
- Red
by strontium nitrate
- Green
by barium nitrate or chlorate
- Blue
by copper compounds
- Orange/amber
by charcoal or other carbon or iron compounds
Deep
blue and purple are the most difficult fireworks colors to create because
they have a very narrow band on the colour spectrum, requiring the chemical
reaction to be absolutely perfect. In fact, the creation of a deep blue
flame remains one of the great unsolved challenges to pyrotechnicians.
However, blue and green are considered the most dangerous colors to produce.